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Please use this identifier to cite or link to this item: http://hdl.handle.net/10928/144

Title: N-置換芳香族アミド結合を使ったらせんおよび環状分子の合成
Other Titles: Synthesis of Helical and Cyclic Molecules Composed of N-Substituted Aromatic Amide Bonds
Authors: 横山, 明弘
Keywords: helix
Issue Date: 1-Dec-2011
Publisher: 成蹊大学理工学部
Abstract: Oligomers and polymers with cyclic and helical structure were synthesized by taking advantage of cis-conformation of N-substituted aromatic amide bonds. A series of single crystal X-ray analyses revealed that 4-(methylamino)benzoic acid oligomers adopted helical conformation with three monomer units per turn in the crystal. The CD spectra and their theoretical analyses indicated that poly(N-subsritutedp-benzamide)favors similar helical conformation in solution. On the other hand, cyclic molecules with inner cavity were synthesized by condensation of trans-stilbene and diphenylacetylene monomers under polymerization conditions.
URI: http://hdl.handle.net/10928/144
Appears in Collections:第48巻第2号

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