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Please use this identifier to cite or link to this item: http://hdl.handle.net/10928/282

Title: らせん不斉を有する (Z)-アゾベンゼンの合成と絶対立体配置
Other Titles: Synthesis and Absolute Configuration of Helical (Z)-Azobenzenes
Authors: 高石, 和人
TAKAISHI, Kazuto
Keywords: Azobenzene
Binaphthyl
Helicity
Axial chilality
Issue Date: 1-Dec-2012
Publisher: 成蹊大学理工学部
Abstract: The conformation of several binaphthyl-azobenzene dyads and oligonaphthyl-azobenzene dyads with an emphasis on the twist pattern of the helical (Z)-azobenzene moiety was researched. 2,2'-Linked-(R)-binaphthyl induced (Z,P)-azobenzene, whereas symmetrically 7,7'-linked-(R)-binaphthyl induced (Z,M)-azobenzene. A systematic and simple induction of asymmetrical azobenzenes was structured using common binaphthyl skeletons.
URI: http://hdl.handle.net/10928/282
Appears in Collections:第49巻第2号

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