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SEIKEI University Repository >
01：紀要(Bulletin) >
11：理工学研究報告 >
第49巻第2号 >
Please use this identifier to cite or link to this item:
http://hdl.handle.net/10928/282
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| Title: | らせん不斉を有する (Z)-アゾベンゼンの合成と絶対立体配置 |
| Other Titles: | Synthesis and Absolute Configuration of Helical (Z)-Azobenzenes |
| Authors: | 高石, 和人
TAKAISHI, Kazuto |
| Keywords: | Azobenzene
Binaphthyl
Helicity
Axial chilality |
| Issue Date: | 1-Dec-2012 |
| Publisher: | 成蹊大学理工学部 |
| Abstract: | The conformation of several binaphthyl-azobenzene dyads and oligonaphthyl-azobenzene dyads with an emphasis on the twist pattern of the helical (Z)-azobenzene moiety was researched. 2,2'-Linked-(R)-binaphthyl induced (Z,P)-azobenzene, whereas symmetrically 7,7'-linked-(R)-binaphthyl induced (Z,M)-azobenzene. A systematic and simple induction of asymmetrical azobenzenes was structured using common binaphthyl skeletons. |
| URI: | http://hdl.handle.net/10928/282 |
| Appears in Collections: | 第49巻第2号
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