SEIKEI University Repository >
01:紀要(Bulletin) >
11:理工学研究報告 >
第50巻第2号 >
このアイテムの引用には次の識別子を使用してください:
http://hdl.handle.net/10928/441
|
タイトル: | 燃料電池用水素製造を目的としたジメチルエーテル水蒸気改質のためのCu系スピネル型複合酸化物触媒の開発 |
その他のタイトル: | Development of Cu-based Spinel Catalyst for Steam Reforming of Dimethyl Ether for Hydrogen Production |
著者: | 霜田, 直宏 SHIMODA, Naohiro |
キーワード: | hydrogen spinel oxide catalyst dimethyl ether fuel cell |
発行日: | 2013年12月1日 |
出版者: | 成蹊大学理工学部 |
抄録: | This work focused on the Cu-based spinel type oxide catalysts for the steam reforming of dimethyl ether (DME SR) reactions. Among Cu-based spinel-oxides, CuFe_2O_4 spinel and γ-Al_2O_3 composite catalyst exhibited the highest activity for DME SR. Reduction behavior, crystal property, and Cu oxidation state of spinel catalysts were strongly affected by B metal elements. The heat treatment temperature range of 700-800℃ is most effective to enhance the catalytic performance due to the new phase of Cu-Fe-AlO_4 formation by solid-state reaction at the interface between CuFe_2O_4 and γ-Al_2O_3. No degradation could be observed for the catalyst subjected to the cooling-heating process in O_2 atmosphere which is assumed the daily start-up and shut-down (DSS) operation. The degraded catalyst after the DSS operation in steam could be recovered by the heat treatment in air at 375℃, because the active sites of γ-Al_2O_3 were regenerated and the coke deposits were removed. |
URI: | http://hdl.handle.net/10928/441 |
出現コレクション: | 第50巻第2号
|
このリポジトリに保管されているアイテムは、他に指定されている場合を除き、著作権により保護されています。
|